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Formation of [CoF 6] 3Θ ion:. Oxidation state of central metal Co is +3. Valence shell electronic configuration of Co 3⊕ is; Six fluoride F Θ ligands, thus the number of vacant metal ion orbitals required for bonding with ligands would be six.; Complex is high spin, which means the pairing of electrons will not take place prior to hybridisation.


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Solution. The atomic number of Co is 27 and its valence shell electronic configuration is 3d 7 4 s2. Co is in +3 oxidation state in the complex [CoF 6] 3−. Hence, [CoF 6] 3− is sp 3 d 2 hybridised and it is octahedral in shape. Concept: Bonding in Coordination Compounds - Magnetic Properties of Coordination Compounds.


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Solution. [CoF 6]3− is a paramagnetic complex ion due to presence of 4 unpaired electrons. Co3+ ion has 3d6 outer electronic configuration with 4 unpaired electrons. In the complex [CoF 6]3−, the oxidation number of Co is +3. The outer electronic configuration of Co3+ ion is 3d6. It can also be written as t4 2ge2 g.


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Density functional theory calculations (DFT), as well as hybrid methods (B3LYP) for B18N18-[CoF6]3− complex have been carried out to study the non-bonded interaction. The geometry of the B18N18 has been optimized at B3LYP method with EPR-II basis set and geometry of the [CoF6]3− have been optimized at B3LYP method with Def2-TZVP basis set and Stuttgart RSC 1997 Effective Core Potential.


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The second element, chlor ine, becomes chlor ide, and we attach the correct numerical prefix ("tetra-") to indicate that the molecule contains four chlorine atoms. Putting these pieces together gives the name carbon tetrachloride for this compound. Example 4.3.2 4.3. 2. Write the molecular formula for each compound.


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Q. Write the hybridisation and number of unpaired electrons in the complex [CoF 6]3−. (Atomic No. of Co =27 ). Q. Hybridisation noticed in CO2 and CO is: Q. On the basis of valence bond theory explain the oxidation state, hybridisation,geometry and magnetic nature of metal in complex [CoF 6]3−. Q. (a) Write the formula of the following.